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  • 标题:Synthesis of Trimethylolpropane Esters of Calophyllum Methyl Esters : Effect of Temperature and Molar Ratio
  • 本地全文:下载
  • 作者:Yeti Widyawati ; Ani Suryani ; Muhammad Romli
  • 期刊名称:International Journal of Renewable Energy Development (IJRED)
  • 印刷版ISSN:2252-4940
  • 出版年度:2014
  • 卷号:3
  • 期号:3
  • 页码:188-192
  • DOI:10.14710/ijred.3.3.188-192
  • 语种:English
  • 出版社:Center of Biomass & Renewable Energy, Dept. of Chemical Engineering, Diponegoro University
  • 摘要:Trimethylolpropane esters were synthesized by transesterification of calophyllum methyl esters and trimethylolpropane using a calcium oxide as the catalyst. The results showed that the optimal reaction conditions (temperature: 130 0 C, reaction time: 5 h, reactant molar ratio: 3.9:1, catalyst amount 3%w/w, and formed trimethylolpropane ester of 79.0% were obtained. The basic physicochemical properties of the trimethylolpropane esters were the following : kinematic viscosities of 56.40 cSt and 8.8 cSt at 40 0 C and 100 0 C, viscosity index 193, flash point 218 0 C and pour point -3 0 C. So Methyl esters of fatty acids of would callophylum methyl ester is good raw material for the synthesis of lubricating oils.
  • 关键词:callophylum methyl ester, transesterification;calcium oxide;trimethylolpropane esters
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