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  • 标题:Electrochemical performance of zirconia/graphene oxide nanocomposites cathode designed for high power density supercapacitor
  • 本地全文:下载
  • 作者:Harish Mudila ; Harish Mudila ; Sweta Rana
  • 期刊名称:Journal of Analytical Science and Technology
  • 电子版ISSN:2093-3371
  • 出版年度:2016
  • 卷号:7
  • 期号:1
  • 页码:1-11
  • DOI:10.1186/s40543-016-0084-7
  • 语种:English
  • 出版社:Korea Basic Science Institute
  • 摘要:Abstract Background Carbon-based metal oxide nanocomposites are always been the prime material for study in the field of energy storage due to their rich abundance, low toxicity, high surface area, electrical conductivity and diverse oxidation states. Methods In this direction, novel zirconia/graphene oxide (ZrO2/GO) nanocomposites are fabricated on the surface of 316 stainless steel for studying their specific capacitance and power performance. ZrO2 and GO in varying mass ratio (1:1, 1:2, and 2:1) were used to fabricate the electroactive material. The physical interaction between the two was determined by Fourier transform-infrared, X-ray diffraction and scanning electron microscopy. TG-DTA-DG informs about the exhibited thermal property by the variants. The cyclic voltammetry was done to study the specific capacitance of the electroactive materials with reference to Ag/AgCl at scan rate (V/s) ranging 0.15–0.001 in 1.0 M KOH. The specific capacitance of ZrO2 was found to be 17.13 Fg−1 at 0.001 Vs−1. The representative (nanocomposite) NC-II shows the maximum specific capacitance of 299.26 Fg−1 at similar rate of scan with power density of 59.40 W/kg. Conclusion The nanocomposites show comparable level of charge-discharge behavior with long-term cycleability, suggesting that fabricated ZrO2/GO nanocomposite electrodes are promising candidate for the high-performance energy storage devices. Graphical abstract Decomposition of electroactive material and electrochemical setup
  • 关键词:Zirconium oxide;Graphene oxide;Specific capacitance;Cyclic voltammetry
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