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  • 标题:Synthesis of visible light active doped TiO2 for the degradation of organic pollutants—methylene blue and glyphosate
  • 本地全文:下载
  • 作者:Khalid Umar ; Khalid Umar ; Azmi Aris
  • 期刊名称:Journal of Analytical Science and Technology
  • 电子版ISSN:2093-3371
  • 出版年度:2016
  • 卷号:7
  • 期号:1
  • 页码:1-8
  • DOI:10.1186/s40543-016-0109-2
  • 语种:English
  • 出版社:Korea Basic Science Institute
  • 摘要:Abstract Background A simple hydrothermal process was applied to synthesize the doped TiO2 particles with different concentrations as well as different metal ions (Mn, Ce and La). Methods The synthesis of Mn-doped-TiO2 nanoparticles was done by using a hydrothermal method from hydrolysis of titanium tetrachloride in aqueous solution. The photocatalytic activities were checked by studying the degradation of two model organic pollutants. Results The material was characterized by X-ray diffraction, scanning electron microscopy, and UV–Visible spectroscopy. The X-ray diffraction pattern studied for doped TiO2 particles suggests the anatase phase with a crystalline nature. Doped TiO2 particles showed a porous and complex nature with a highly rough surface. The photocatalytic activity of Mn- Ce- and La-doped TiO2 with different metal-ion concentrations of 0.15-0.60% show that the degradation rate of all of the pollutants increases with an increase in the dopant concentration from 0.15 to 0.45%, and a further increase in the dopant concentration decreased the degradation rate. Conclusions The results indicate that TiO2 with a concentration of 0.45% for all metal ions (Mn, Ce and La) shows the highest activity. Among studied dopent TiO2 with Mn (0.45%) showed the best degradation activity.
  • 关键词:Doped TiO;2;Photocatalytic degradation;Pesticide;Dye;Visible light
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