摘要：Chemical shifts and full widths at half maximum intensity (FWHM) of Kα and Kβ1,3 x-ray emission lines and differences of full widths at half maximum intensity (ΔFHWM) using metallic element as reference for these emission lines were measured for oxygen compounds of elements in the range 22 ≤ Z ≤ 29 with a Wavelength-Dispersive X-Ray Fluorescence spectrometry (WDXRF). It was also found larger chemical shifts and FWHM for Kβ1,3 lines than those of Kα ones. It should be noted that the magnitude of chemical shifts increases with increase in the numbers of ligand atom.
