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  • 标题:Hexavalent chromium removal from aqueous solution by adsorbents synthesized from groundwater treatment residuals
  • 本地全文:下载
  • 作者:Chi-Chuan Kan ; Chi-Chuan Kan ; Aldwin H. Ibe
  • 期刊名称:Sustainable Environment Research
  • 印刷版ISSN:2468-2039
  • 出版年度:2017
  • 卷号:27
  • 期号:4
  • 页码:163-171
  • DOI:10.1016/j.serj.2017.04.001
  • 语种:English
  • 出版社:Elsevier
  • 摘要:Abstract In this study, silica sand coated with groundwater treatment residuals was used as adsorbents for the removal of hexavalent chromium from synthetic wastewater. Batch adsorption experiments were conducted to evaluate the effects of initial Cr(VI) concentration, solution pH, adsorbent dosage, solution temperature, contact time, as well as ionic strength on Cr(VI) removal. Results show that low solution pH and high ionic strength improve Cr(VI) adsorption onto the residual coated sand. At pH 4, the highest adsorption capacity was computed at 0.27 mg g−1. The Freundlich isotherm model best described the adsorption process. From 298 to 318 K, the high correlation of the kinetic data with the pseudo-second order model (R 2  > 0.981) and a highly positive activation energy value (22.7 kJ mol−1) indicate that chemisorption is the rate-controlling step of the adsorption process.
  • 关键词:KeywordsenGroundwater treatment residualsHexavalent chromiumBatch adsorptionIsothermKineticsThermodynamics
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