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  • 标题:Synthesis and characterization of grafted acrylonitrile on polystyrene modified with activated carbon using gamma-irradiation
  • 本地全文:下载
  • 作者:Muhammed Mizher Radhi ; Wee Tee Tan ; Mohamad Zaki B. Ab Rahman
  • 期刊名称:Scientific Research and Essays
  • 印刷版ISSN:1992-2248
  • 出版年度:2012
  • 卷号:7
  • 期号:7
  • 页码:790-795
  • DOI:10.5897/SRE11.1286
  • 语种:English
  • 出版社:Academic Journals
  • 摘要:Acrylonitrile was successfully grafted on polystyrene modified with activated carbon using gamma-irradiation technique. This process was carried out modified at various gamma dose (0.2 to 1.5 Mrad). The new grafted polymer (GP) was characterized and its properties were investigated. In this study, it was found that 2 g of polystyrene, 90% (w/w) acrylonitrile monomer, 2% (w/w) ferrous ammonium sulfate (FAS) catalyst, 1 mg activated carbon powder and 1.25 Mrad gamma dose are the optimized conditions required for the polymerization of GP.The grafted polymer was proved by Fourier transform infrared (FTIR), thermo gravimetric analysis (TGA) and UV-visible spectroscopy. A mechanism is presented to explain the formation of GP.
  • 关键词:Activated carbon; polystyrene; acrylonitrile; gamma-irradiation; ferrous ammonium sulfate (FAS) " />
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