标题：Investigation of intermolecular interactions in binary liquid mixtures of [Bmim][NTf 2] and propylene carbonate at different temperatures using ultrasonic, optical and FT-IR studies
期刊名称：Karbala International Journal of Modern Science
印刷版ISSN：2405-609X
电子版ISSN：2405-609X
出版年度：2017
卷号：3
期号：4
页码：279-286
DOI：10.1016/j.kijoms.2017.07.002
语种：English
出版社：Elsevier
摘要：AbstractSpeeds of sound and refractive indices of [Bmim][NTf2]+propylene carbonate mixtures have been measured experimentally over the entire composition range at 303.15, 308.15, 313.15, 318.15 and 323.15 K, under 101.3 kPa pressure. Semi empirical relations of speed of sound and refractive index have been applied for the liquid mixtures in terms of the pure components proposed by different investigators. The deviation of refractive index on volume fraction basis(ΔϕnD)reported for the binary mixture and fitted using Redlich-Kister polynomial equation. The measured and computed data have been used to interpret intermolecular interactions between unlike molecules upon mixing. This was further supported by FTIR spectroscopy.Graphical abstractDisplay Omitted
关键词：Bmim][NTf;2;];Propylene carbonate;Speed of sound;Refractive index;FTIR spectroscopy
