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  • 标题:Gold nanoparticles stabilized by starch polymer and their use as catalyst in homocoupling of phenylboronic acid
  • 本地全文:下载
  • 作者:Kittiyaporn Wongmanee ; Kittiyaporn Wongmanee ; Sureeporn Khuanamkam
  • 期刊名称:Journal of King Saud University - Science
  • 印刷版ISSN:1018-3647
  • 出版年度:2017
  • 卷号:29
  • 期号:4
  • 页码:547-552
  • DOI:10.1016/j.jksus.2017.08.007
  • 语种:English
  • 出版社:Elsevier
  • 摘要:Graphical abstractDisplay OmittedAbstractIn this study, gold nanoparticles (Au NPs) stabilized by a starch polymer have been successfully prepared and characterized via a number of techniques including X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), UV-visible spectroscopy (UV-vis), transmission electron microscopy (TEM), and dynamic light scattering (DLS) measurements. The catalytic activity of starch-stabilized Au NPs was also examined toward the homocoupling of phenylboronic acid in water using oxygen in air as oxidant at an ambient temperature (25±1°C). Several parameters including the catalyst loading, base equivalent (eq.), base type, and reaction time were studied. This study offers a simple, inexpensive and environmentally friendly procedure for the stabilization of colloidal gold catalysts using a hydroxyl-rich structure of starch polymer with a great promise through potential applications in related fields.
  • 关键词:Gold nanoparticles;Starch support;Homocoupling;Phenylboronic acid
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