期刊名称：Journal of Environmental Analytical Chemistry
电子版ISSN：2380-2391
出版年度：2017
卷号：4
期号：2
页码：1-4
DOI：10.4172/2380-2391.1000193
语种：English
出版社：OMICS International
摘要：A new method was developed to determine the oil and grease in water by HPLC-Vis fluorescence technique. Ultrasonication liquid-liquid extraction method was applied by using 1 ml of toluene to 100 ml of water. The analysis was carried out on a LC-10AT-VP chromatograph with a fluorescence RF. 10 a syknm detector equipped with a varian CN (250 × 4.6 μm) Column. The separation was preformed isocratically using a mixture of 90% solvent (n-Hexane) with 10% solvent (Toluene). Asphaltenic compounds were established to be the main fluorescence chromophores (excitation wave length at 420 nm and emission wave length at 500 nm). The correlation coefficient was (0.992), recovery ranged from 92% to 108% and the limit of detection was found to be 0.06 μg.L-1. The method can be utilized successfully for determination of oil and grease in water samples.
关键词：Crude oil; Oil; Grease; HPLC-Vis fluorescence; Method validation; Water environment
