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  • 标题:Improved electrochemical performance of 5 V spinel LiNi 0.5Mn 1.5O 4 by La 2O 3 surface coating for Li-ion batteries
  • 本地全文:下载
  • 作者:Aijia Wei ; Wen Li ; Lihui Zhang
  • 期刊名称:MATEC Web of Conferences
  • 电子版ISSN:2261-236X
  • 出版年度:2018
  • 卷号:175
  • DOI:10.1051/matecconf/201817501030
  • 语种:English
  • 出版社:EDP Sciences
  • 摘要:LiNi0.5Mn1.5O4coated with 1.5 wt.% La2O3was prepared and investigated as cathode materials for lithium ion batteries. The samples was characterized by XRD, SEM and EDX. After the 1.5 wt.% La2O3coating, the lattice structure of LiNi0.5Mn1.5O4is not destroyed and a La2O3coating layer has formed on the surface of LiNi0.5Mn1.5O4particles. The 1.5 wt.% La2O3-coated LiNi0.5Mn1.5O4exhibits a higher rate capacity, with discharge capacity between 3.5 and 5 V of 131.9, 127.1, 126.5, 120.7, 114.1 and 101.5 mAh g-1at rates of 0.2, 0.5, 1, 2, 3 and 5 C (1 C = 140 mAh g-1), respectively. The results indicate that the La2O3coating could reduce the electrode polarization and enhance the rate capacities.
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