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  • 标题:A new rhodamine fluorescent OFF-ON-OFF probe for selective sensing of Fe 3+ and AcO - in aqueous media and living cells
  • 本地全文:下载
  • 作者:Qinglei Liu ; Huimin Liu ; Yanan Lei
  • 期刊名称:MATEC Web of Conferences
  • 电子版ISSN:2261-236X
  • 出版年度:2018
  • 卷号:238
  • DOI:10.1051/matecconf/201823804002
  • 语种:English
  • 出版社:EDP Sciences
  • 摘要:A new fluorescent chemosensor for Fe3+ was developed based on a rhodamine platform. L displayed highly selective and sensitive “OFF-ON” fluorescence response and naked-eye color change to Fe3+ in aqueous solution. The resulting L-Fe3+ complex was found to act as a selective“ ON-OFF” fluorescence probe for AcO- against common anions and cations with a Fe3+ displacement approach. The detection limits of L to Fe3+ and L-Fe3+ complex to AcO- were estimated to be 6.04×10-8 mol/L and 7.51×10-8 mol/L, respectively. The good biocompatibility of L enabled the investigation of fluorescent response for Fe3+ and AcO- in living Ana-1 cells by confocal microscope.
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