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  • 标题:GREEN METHODS FOR OXIDATION OF AN AROMATIC DIKETONE TO AN AROMATIC ANHYDRIDE: OXIDATION OF ACEANTHRAQUINONE
  • 本地全文:下载
  • 作者:Shidokht Nazari ; Khashayar Ghandi
  • 期刊名称:Fresenius Environmental Bulletin
  • 印刷版ISSN:1018-4619
  • 出版年度:2015
  • 卷号:24
  • 期号:4A
  • 页码:1350-1355
  • 语种:English
  • 出版社:PSP Publishing
  • 摘要:We studied the potential green methods of the oxidation of aceanthraquinone to anthracene-1,9-dicarboxylic anhydride. The potentials for both a solvent-free process and a closed microwave-based reaction using ethanol as a solvent are compared with the existing process in the literature, which is based on a reaction in 1, 4-dioxane with a high concentration of base at reflux. The thermal solvent free process discussed herein has reasonable yields. The processes still need to be optimized to improve reaction time.
  • 关键词:green chemistry; solvents; solvent-free reactions; microwave; oxidation; aromatic diketones
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