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  • 标题:SYNTHESIS AND PROPERTIES OF HIGH OIL ABSORPTIVE CROSS-LINKED LAURYL ACRYLATE–STYRENE–EGDMA COPOLYMERS
  • 本地全文:下载
  • 作者:Changwei Zhao ; Jun Wang ; Ye Li
  • 期刊名称:Fresenius Environmental Bulletin
  • 印刷版ISSN:1018-4619
  • 出版年度:2015
  • 卷号:24
  • 期号:8
  • 页码:2460-2469
  • 语种:English
  • 出版社:PSP Publishing
  • 摘要:Crosslinked copolymers for oil absorption were synthesized by copolymerizing styrene (St) with lauryl acrylate (LA), with ethylene glycol dimethacrylate as crosslinking agent. Suspension polymerization was conducted using benzoyl peroxide as initiator. The crosslinking reaction mechanism and the structure of the composite were characterized by FT-IR analysis. Effects of different polymerization conditions were studied through oil absorption tests. The oil absorbency was influenced mainly by the degree of crosslinking and the LA/St ratio. Optimal oil absorbency was obtained for St/LA = 1. The absorbency of copolymers was higher for the aromatic series by the affinity investigation toward different organic solutions.
  • 关键词:crosslinking; LA–St copolymers; EGDMA; suspension polymerization; oil absorption; swelling property
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