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  • 标题:Extraction of Nickel from Spent Catalyst Using EDTA as Chelating Agent
  • 本地全文:下载
  • 作者:Rachit Oza ; Nikhil Shah ; Sanjay Patel
  • 期刊名称:Nature, Environment and Pollution Technology
  • 印刷版ISSN:0972-6268
  • 出版年度:2011
  • 卷号:10
  • 期号:2
  • 语种:English
  • 出版社:Technoscience Publications
  • 摘要:The extraction of nickel from spent catalyst of primary steam reformer from a nearby fertilizer plant usingchelation method is reported in this paper. The chelation was carried out using a di-sodium salt of EDTA(ethylene diamine tetra acetic acid) as a chelating agent. The Ni-EDTA complex formed was dechelatedusing nitric acid as a solvent resulting into the formation of nickel nitrate (NiNO 3 ) and recovery of EDTA. Therecovered EDTA was used for subsequent experiments. The objective was to evaluate nickel removal efficiencyof EDTA and reusability of recovered EDTA. The effect of EDTA concentration, time of chelation, catalyst toliquid ratio (S:L) and temperature of chelation were studied in detail. The extraction was up to 95% under thefollowing conditions: 1M concentration of EDTA, solid to liquid ratio 1:10 (g/mL), particle size 1-2 mm, pH10, 7 hours of chelation time, 400 rpm and 90°C.
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