摘要：Microwave-assisted synthesis of zirconium (Zr) based metal organic frameworks (MOFs) were performed and the yield and porous property of UiO-67 was optimized by varying the quantity of the modulator, reaction time and temperature. It was found that (i) an increase in the amount of modulator enhanced the specific surface area and pore volume of UiO-67 due to the promotion of linker deficiency; and (ii) the presence of modulators influenced the number of nuclei (and hence the crystal size) and the yield.
