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  • 标题:Degradation Mechanisms in Smectitic Clay for Isolating Radioactive Waste
  • 本地全文:下载
  • 作者:Roland Pusch ; Jörn Kasbohm ; Thao Hoang-Minh
  • 期刊名称:Journal of Earth Sciences and Geotechnical Engineering
  • 印刷版ISSN:1792-9040
  • 出版年度:2019
  • 卷号:9
  • 期号:3
  • 页码:117-132
  • 语种:English
  • 出版社:Scienpress Ltd
  • 摘要:Most of the proposed techniques for chemical shielding of radioactive waste impliesuse of smectite clay, which degrades according to a well-known scheme. Since such“buffer” clay has to serve for many thousands of years, the mechanisms in theunavoidable long-term degradation process must be understood and accounted foras described in the paper. In addition to conversion of smectite to non-expandableminerals cementation by precipitation of siliceous matter created in the degradationprocess is of concern since it can reduce the self-sealing capacity of desiccated ormechanically damaged clay.
  • 关键词:Smectite clays; diffractogram; radioactive wastes; montmorillonite;XRD; TEM; Holmehus clay.
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