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  • 标题:Deactivation of Ce-Ti Oxide Catalyst by K3PO4 for the Selective Catalytic Reduction of NO with NH3
  • 本地全文:下载
  • 作者:Ye Jiang ; Chengzhen Lai ; Shaojun Liu
  • 期刊名称:Aerosol and Air Quality Research
  • 印刷版ISSN:1680-8584
  • 出版年度:2019
  • 卷号:19
  • 期号:2
  • 页码:422-430
  • DOI:10.4209/aaqr.2018.06.0215
  • 语种:English
  • 出版社:Chinese Association for Aerosol Research in Taiwan
  • 摘要:The effect of K3PO4 on the selective catalytic reduction of NO with NH3 over a Ce-Ti oxide catalyst was investigated using XRD, BET, XPS, NH3-TPD, H2-TPR and activity measurements. The results showed that K3PO4 deactivated the Ce-Ti oxide catalyst seriously. The drop in the amount of Ce3+ was accompanied by a decrease in oxygen vacancies and active surface oxygen species, which was disadvantageous to the SCR reaction over the Ce-Ti oxide catalyst. In addition, a reduction in the Brønsted surface acidity and reducibility was also responsible for the deactivation of the Ce-Ti oxide catalyst by K3PO4.
  • 关键词:Selective catalytic reduction;NO;NH3;K3PO4;Ce-Ti oxide;Activity
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