标题：A broad range of organophosphate tri- and di-esters in house dust from Adelaide, South Australia: Concentrations, compositions, and human exposure risks
摘要：Highlights•Ubiquitous presence of a suite of tri- & di-OPEs discovered in Adelaide house dust.•TPHP-based OPEs emerged in house dust with combined levels surpassing that of TPHP.•Di-OPEs constituted ~13% of total tri-OPE concentrations in Adelaide house dust.•The complexity of the OPE group raises concern on potential human exposure risks.AbstractThis study aimed to investigate the occurrences of a suite of thirty-one organophosphate tri-esters (tri-OPEs) and six di-esters (di-OPEs) in house dust collected from Adelaide, South Australia. The results demonstrate ubiquitous presence of most OPEs in Adelaide house dust, with median concentration of 40,200 and 5260 ng/g dry weight for ∑tri-OPEs and ∑di-OPEs, respectively. A number of emerging OPEs with chemical structures resembling that of triphenyl phosphate (TPHP), including bisphenol A bis(diphenyl phosphate) (BPA-BDPP), cresyl diphenyl phosphate (CDP), isodecyl diphenyl phosphate (IDDPP), resorcinol-bis(diphenyl)- phosphate (RDP), as well as a suite of isopropylated ortert-butylated triarylphosphate ester isomers (ITPs or TBPPs), were frequently detected with combined levels surpassing that of TPHP. The investigated di-OPEs, predominated by DPHP, consisted of approximately 13% of the ∑tri-OPEs concentrations. Median concentration ratios of diphenyl phosphate (DPHP) and bis(2-ethylhexyl) phosphate (BEHP) to their respective tri-OPEs [i.e., TPHP and tris(2-ethylhexyl) phosphate (TEHP)
