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  • 标题:iEucheuma cottonii/i Seaweed-Based Biochar for Adsorption of Methylene Blue Dye
  • 本地全文:下载
  • 作者:Anwar Ameen Hezam Saeed ; Noorfidza Yub Harun ; Suriati Sufian
  • 期刊名称:Sustainability
  • 印刷版ISSN:2071-1050
  • 出版年度:2020
  • 卷号:12
  • 期号:24
  • 页码:10318
  • DOI:10.3390/su122410318
  • 语种:English
  • 出版社:MDPI, Open Access Journal
  • 摘要:Pollution from dye containing wastewater leads to a variety of environmental problems, which can destroy plant life and eco-systems. This study reports development of a seaweed-based biochar as an adsorbent material for efficient adsorption of methylene blue (MB) dye from synthetic wastewater. The iEucheuma cottonii/i seaweed biochar was developed through pyrolysis using a tube furnace with Nsub2/sub gas, and the properties were later improved by sulfuric acid treatment. The adsorption studies were conducted in a batch experimental setup under initial methylene blue concentrations of 50 to 200 mg/L, solution pH of 2 to 10, and temperature of 25 to 75 °C. The characterization results show that the developed biochar had a mesoporous pore morphology. The adsorbent possessed the surface area, pore size, and pore volume of 640 msup2/sup/g, 2.32 nm, and 0.54 cmsup3/sup/g, respectively. An adsorption test for 200 mg/L of initial methylene blue at pH 4 showed the best performance. The adsorption data of the seaweed-based biochar followed the Langmuir isotherm adsorption model and the pseudo-second-order kinetic model, with the corresponding Rsup2/sup of 0.994 and 0.995. The maximum adsorption capacity of methylene blue using the developed seaweed‑based biochar was 133.33 mg/g. The adsorption followed the chemisorption mechanism, which occurred via the formation of a monolayer of methylene blue dye on the seaweed-based biochar surface. The adsorption performance of the produced seaweed biochar is comparable to that of other commercial adsorbents, suggesting its potential for large-scale applications.
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