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  • 标题:Fabrication of Dy 2 O 3 Transparent Ceramics by Vacuum Sintering Using Precipitated Powders
  • 本地全文:下载
  • 作者:Dianjun Hu ; Xin Liu ; Ziyu Liu
  • 期刊名称:Maine Policy Review
  • 印刷版ISSN:2312-7481
  • 出版年度:2021
  • 卷号:7
  • 期号:1
  • 页码:6
  • DOI:10.3390/magnetochemistry7010006
  • 语种:English
  • 出版社:The University of Maine
  • 摘要:As a kind of promising material for a Faraday isolator used in the visible and near infrared range, Dy<sub>2</sub>O<sub>3</sub> transparent ceramics were prepared by vacuum sintering from the nano-powders synthesized by the liquid precipitation method using ammonium hydrogen carbonate as precipitant with no sintering aids. The synthesized precursor was calcinated at 950 °C–1150 °C for 4 h in air. The influences of the calcination temperature on the morphologies and phase composition of Dy<sub>2</sub>O<sub>3</sub> powders were characterized. It is found that the Dy<sub>2</sub>O<sub>3</sub> powder calcinated at 1000 °C for 4 h is superior for the fabrication of Dy<sub>2</sub>O<sub>3</sub> ceramics. The Dy<sub>2</sub>O<sub>3</sub> transparent ceramic sample prepared by vacuum sintering at 1850 °C for 10 h, and subsequently with air annealing at 1400 °C for 10 h, from the 1000 °C-calcined Dy<sub>2</sub>O<sub>3</sub> powders, presents the best optical quality. The values of in-line transmittance of the optimal ceramic specimen with the thickness of 1.0 mm are 75.3% at 2000 nm and 67.9% at 633 nm. The Verdet constant of Dy<sub>2</sub>O<sub>3</sub> ceramics was measured to be −325.3 ± 1.9 rad/(T·m) at 633 nm, about 2.4 times larger than that of TGG (Tb<sub>3</sub>Ga<sub>5</sub>O<sub>12</sub>) single crystals.
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