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  • 标题:Spectroscopic characterization of electronic structures of ultra-thin single crystal La 0.7Sr 0.3MnO 3
  • 本地全文:下载
  • 作者:Chun-Chien Chiu ; Yao-Wen Chang ; Yu-Cheng Shao
  • 期刊名称:Scientific Reports
  • 电子版ISSN:2045-2322
  • 出版年度:2021
  • 卷号:11
  • DOI:10.1038/s41598-021-84598-8
  • 语种:English
  • 出版社:Springer Nature
  • 摘要:We have successfully fabricated high quality single crystalline La 0.7Sr 0.3MnO 3 (LSMO) film in the freestanding form that can be transferred onto silicon wafer and copper mesh support. Using soft x-ray absorption (XAS) and resonant inelastic x-ray scattering (RIXS) spectroscopy in transmission and reflection geometries, we demonstrate that the x-ray emission from Mn 3 s-2 p core-to-core transition (3 sPFY) seen in the RIXS maps can represent the bulk-like absorption signal with minimal self-absorption effect around the Mn L 3-edge. Similar measurements were also performed on a reference LSMO film grown on the SrTiO 3 substrate and the agreement between measurements substantiates the claim that the bulk electronic structures can be preserved even after the freestanding treatment process. The 3 sPFY spectrum obtained from analyzing the RIXS maps offers a powerful way to probe the bulk electronic structures in thin films and heterostructures when recording the XAS spectra in the transmission mode is not available.
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