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  • 标题:Highly conductive colloidal carbon based suspension for flow-assisted electrochemical systems
  • 本地全文:下载
  • 作者:Marco S. Alfonso ; Hélène Parant ; Jinkai Yuan
  • 期刊名称:iScience
  • 印刷版ISSN:2589-0042
  • 出版年度:2021
  • 卷号:24
  • 期号:5
  • 页码:1-21
  • DOI:10.1016/j.isci.2021.102456
  • 语种:English
  • 出版社:Elsevier
  • 摘要:SummaryCarbon suspension electrodes are promising for flow-assisted electrochemical energy storage systems. They serve as flowable electrodes in electrolyte solutions of flow batteries, or flow capacitors. They can also be used for other applications such as capacitive deionization of water. However, developments of such suspensions remain challenging. The suspensions should combine low viscosity and high electronic conductivity for optimized performances. In this work, we report a flowable aqueous carbon dispersion which exhibits a viscosity of only 2 Pa.s at a shear rate of 5 s−1for a concentration of particles of 7 wt%. This suspension displays an electronic conductivity of 65 mS/cm, nearly two orders of magnitude greater than previously investigated related materials. The investigated suspensions are stabilized by sodium alginate and arabic gum in the presence of ammonium sulfate. Their use in flowable systems for the storage and discharge of electrical charges is demonstrated.Graphical abstractDisplay OmittedHighlights•Fluid and highly conductive carbon-based suspensions are reported•The suspensions are potentially useful for flow-assisted electrochemical applications•Charge and discharge of flowable electrodes is quantitatively demonstratedElectrochemical energy storage; Energy storage; Physical chemistry
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