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  • 标题:Study on novel structure of tris-(4,4′-dimethyl-2,2′-dipyridyl) Nickel salicylic acid boric acid, Ni(C 12H 12N 2) 3●(C 7H 5O 3) 2●(H 3BO 3)
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  • 作者:Xiaoyan Ren ; Haixing Liu ; Yanfang Huo
  • 期刊名称:E3S Web of Conferences
  • 印刷版ISSN:2267-1242
  • 电子版ISSN:2267-1242
  • 出版年度:2021
  • 卷号:252
  • 页码:1-5
  • DOI:10.1051/e3sconf/202125202069
  • 语种:English
  • 出版社:EDP Sciences
  • 摘要:A novel complex Ni(C12H12N2)3●(C7H5O3)2●(H3BO3) has been synthesized from a hydrothermal reaction and the crystal structure has been determined by means of single-crystal X-ray diffraction. Triclinic, P-1. a= 12.5380(13) Å, b = 13.0100(15) Å, c = 15.1490(18) Å, α= 102.760(3)°, β= 94.480(2)°, γ= 94.540(2)°. V=2390.9(5) Å3. Z=2. R1=0.0661, wR2= 0.2128, T=293(2) K. The Ni atom is coordinated by six N atoms from three 4,4′-dimethyl-2,2′-dipyridyl molecular. The molecular structure stabilized by the O-H…O hydrogen-bonding interactions.
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