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  • 标题:Inversely polarized thermo-electrochemical power generation via the reaction of an organic redox couple on a TiO 2/Ti mesh electrode
  • 本地全文:下载
  • 作者:Hiroto Eguchi ; Takashi Kobayashi ; Teppei Yamada
  • 期刊名称:Scientific Reports
  • 电子版ISSN:2045-2322
  • 出版年度:2021
  • 卷号:11
  • DOI:10.1038/s41598-021-93269-7
  • 语种:English
  • 出版社:Springer Nature
  • 摘要:We demonstrate thermo-electrochemical (TEC) conversion using a biocompatible redox couple of lactic acid and pyruvic acid on earth-abundant TiO 2. The TEC cell exhibited a positive Seebeck coefficient of 1.40 mV K −1. DFT calculations figured out that the adsorption of intermediate species and protons on TiO 2 controls both the redox reaction and current polarity.
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