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  • 标题:The application of zinc citrate for the synthesis of carbon materials
  • 本地全文:下载
  • 作者:Yuliya Sinelnikova ; Nikolai Uvarov
  • 期刊名称:MATEC Web of Conferences
  • 电子版ISSN:2261-236X
  • 出版年度:2021
  • 卷号:340
  • 页码:1-5
  • DOI:10.1051/matecconf/202134001042
  • 语种:English
  • 出版社:EDP Sciences
  • 摘要:Zinc citrate was prepared and its thermal decomposition was investigated by methods of thermogravimetric analysis and differential scanning calorimetry. Products of the thermal decomposition were investigated by X-ray diffraction analysis. The decomposition proceeds at temperatures 50 - 420 °C in three stages and leads to the formation of nanocrystalline ZnO with the average grain size of 23 nm. Subsequently, zinc citrate was used as a precursor of ZnO hard template for preparation of carbon mesoporous materials by the solid template method. The carbon materials were obtained by pyrolysis of polymer matrix of phenol-formaldehyde resin in which zinc citrate was added. It was found that the resulting material has a specific surface area of 1051 m2/g. According to the cyclic voltamperometry data, the material has a specific capacity 40 F/g.
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