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  • 标题:Behaviour of Ionic Liquid-Derived Naphthenate Salts Under Desalting Conditions
  • 本地全文:下载
  • 作者:Azlan Shah Hussain ; Poh Gaik Law ; Jamali Basar
  • 期刊名称:E3S Web of Conferences
  • 印刷版ISSN:2267-1242
  • 电子版ISSN:2267-1242
  • 出版年度:2021
  • 卷号:287
  • 页码:1-7
  • DOI:10.1051/e3sconf/202128704002
  • 语种:English
  • 出版社:EDP Sciences
  • 摘要:Pyrenees crude oil containing high napthenic acids (NAs) content of more than 1.6 mg KOH/g oil was treated with methyltrimethylammonium methylcarbonate [N4441][MeCO3] as to reduce its acidity to the refinery permissible limit of 0.3 mg KOH/g oil. The treated crude oils are subjected to Emulsion Stability Test (EST) as to mimic the operating conditions of a desalter. The results indicate the electrostatic conditions can facilitate the recovery of the napthenate salts post neutralization with high recovery rate of more than 79.6% with basic sediments & water (BSW) to be 1.96%. The conductivity of the treated crude oil also was found to increase as a function of temperature. The ionic liquid mediated-deacidification of crude oil can be performed under existing desalting conditions should the recovery of the naphthenate salts is acceptable at 70%.
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