摘要：SummaryHKUST-1@CMC (HK@CMC) composites that show good acid and alkali resistance and radiation resistance were successfully synthesized by introducing carboxymethyl cellulose (CMC) onto the surface of HKUST-1 using a foaming strategy. For the first time, the composites were explored as efficient adsorbents for U(VI) trapping from aqueous solution, with encouraging results of large adsorption capacity, fast adsorption kinetics, and desirable selectivity toward U(VI) over a series of competing ions. More importantly, a hybrid derivative film was successfully prepared for the dynamic adsorption of U(VI). The results show that ∼90% U(VI) can be removed when 45 mg L−1U(VI) was passed through the film one time, and the removal percentage is still more than 80% even after four adsorption-desorption cycles, ranking one of the most practical U(VI) scavengers. This work offers new clues for application of the Metal-organic-framework-based materials in the separation of radionuclides from wastewater.Graphical abstractDisplay OmittedHighlights•HKUST-1@CMC composites were obtained by using foaming strategy•HKUST-1@CMC composites show good acid and alkali resistance and radiation resistance•HKUST-1@CMC composites have high performance in U(VI) capture from aqueous solution•The derivative film was prepared, and the dynamic adsorption was conductedChemistry; Engineering; Materials science; Materials chemistry; Materials application
