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  • 标题:A magnetic copper organic framework material as an efficient and recyclable catalyst for the synthesis of 1,2,3-triazole derivatives
  • 本地全文:下载
  • 作者:Elham Arefi ; Amir Khojastehnezhad ; Ali Shiri
  • 期刊名称:Scientific Reports
  • 电子版ISSN:2045-2322
  • 出版年度:2021
  • 卷号:11
  • DOI:10.1038/s41598-021-00012-3
  • 语种:English
  • 出版社:Springer Nature
  • 摘要:In this study, a core–shell magnetic metal organic framework (MOF) catalyst was introduced based on Fe 3O 4 magnetic nanoparticles (MNPs) and copper organic frameworks. In this catalyst, Fe 3O 4 MNPs have been coated with MOFs in which copper was the inorganic nodes and 1,3,5-benzenetricarboxylic acid was the organic linkers. Then, the core–shell structures and catalytic efficiency have been confirmed properly and completely with various analyses such as FT-IR, TEM, SEM, TEM mapping, SEM mapping, EDX, PXRD, TGA, ICP and VSM. The Cu moieties in MOF and shell structures can catalyze the synthesis of 1,2,3-triazole derivatives with good to excellent yields in the presence of water as a green solvent. Moreover, this catalyst showed the high reusability due to the super paramagnetic properties.
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