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  • 标题:Sulfonation of Divinylbenzene Adsorbents Packed in a Micro Sampler to Extract Airborne Organic Compounds
  • 本地全文:下载
  • 作者:Po-Jung Huang ; Wen-Hsi Cheng ; Chia-Yu Chang
  • 期刊名称:Aerosol and Air Quality Research
  • 印刷版ISSN:1680-8584
  • 出版年度:2021
  • 卷号:21
  • 期号:11
  • 页码:1-9
  • DOI:10.4209/aaqr.210157
  • 语种:English
  • 出版社:Chinese Association for Aerosol Research in Taiwan
  • 摘要:In this work, sulfonated divinylbenzene (SDVB) adsorbents, with the 60–80 mesh diameter, were packed inside a 22-gauge stainless steel needle to fabricate a sulfonated needle trap sampler (SNTS), which is a micro sampler. An analysis of Fourier-transform infrared spectroscopy (FTIR) scanning data, thermal gravimetric analysis (TGA) data, and scanning electron microscopice (SEM) observations, confirmed the physiochemical characteristics of sulfonated DVB adsorbent resins. A gas mixture of approximately 20 ppm of ethanol, methyl ethyl ketone (MEK), benzene, toluene, ethylbenzene and o-xylene (BTEX) was prepared to evaluate the sampling efficacies of the SNTS. The results reveal that, in 1–2 h, SNTS adsorbed increased 92–116% more methanol and 12–20% more MEK than NTS. The SNTS adsorbed 4–15% less BTEX than the NTS. The tested SNTS exhibited remarkable adsorption capacities of methanol, which emitted in a metal frame manufacturing plant. The SNTS is recommended as an alternative passive sampler to the active adsorbent tubes.
  • 关键词:Sulfonation;Divinylbenzene;Adsorption;Micro sampler;Solid phase;Microextraction
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