摘要:SummaryReversible solid oxide fuel cell (RSOFC) is an energy device that flexibly interchanges between electrical and chemical energy according to people’s life and production needs. The development of cell materials affects the stability and cost of the cell, but also restricts its market-oriented development. After decades of research by scientists, a lot of achievements and progress have been made on RSOFC materials. According to the composition and requirements of each component of RSOFC, this article summarizes the research progress based on materials and discusses the merits and demerits of current cell materials in electrochemical performance. According to the efficiency of different materials in solid oxide fuel cell (SOFC mode) and solid oxide electrolyzer (SOEC mode), the challenges encountered by RSOFC in the operation are evaluated, and the future development of RSOFC materials is boldly prospected.Graphical abstractDisplay OmittedEnergy systems; Materials science; Energy materials