期刊名称：Proceedings of the National Academy of Sciences
印刷版ISSN：0027-8424
电子版ISSN：1091-6490
出版年度：2021
卷号：118
期号：45
DOI：10.1073/pnas.2110427118
语种：English
出版社：The National Academy of Sciences of the United States of America
摘要：Significance
Oxygen is not only crucial for life as we know it but also forms the most abundant element in the outer layers of rocky planets in our own solar system and in exoplanetary systems orbiting other stars. Models for rocky (exo)planets suggest that on the order of 50% of all atoms in their rocky shells are oxygen atoms. Here we provide experimental evidence for a significant effect of planetary oxygen abundance on melting of rocks, showing that higher rock oxygen abundance leads to easier rock melting. This suggests that the extent and vigor of magmatism differ greatly between low-oxygen and high-oxygen exoplanets, opening an avenue to couple future observations of exoplanet atmospheres to interior compositions that cannot be directly observed.
Refractory oxygen bound to cations is a key component of the interior of rocky exoplanets. Its abundance controls planetary properties including metallic core fraction, core composition, and mantle and crust mineralogy. Interior oxygen abundance, quantified with the oxygen fugacity (
fO
2), also determines the speciation of volatile species during planetary outgassing, affecting the composition of the atmosphere. Although melting drives planetary differentiation into core, mantle, crust, and atmosphere, the effect of
fO
2 on rock melting has not been studied directly to date, with prior efforts focusing on
fO
2-induced changes in the valence ratio of transition metals (particularly iron) in minerals and magma. Here, melting experiments were performed using a synthetic iron-free basalt at oxygen levels representing reducing (log
fO
2 = −11.5 and −7) and oxidizing (log
fO
2 = −0.7) interior conditions observed in our solar system. Results show that the liquidus of iron-free basalt at a pressure of 1 atm is lowered by 105 ± 10 °C over an 11 log
fO
2 units increase in oxygen abundance. This effect is comparable in size to the well-known enhanced melting of rocks by the addition of H
2O or CO
2. This implies that refractory oxygen abundance can directly control exoplanetary differentiation dynamics by affecting the conditions under which magmatism occurs, even in the absence of iron or volatiles. Exoplanets with a high refractory oxygen abundance exhibit more extensive and longer duration magmatic activity, leading to more efficient and more massive volcanic outgassing of more oxidized gas species than comparable exoplanets with a lower rock
fO
2.
