期刊名称：Proceedings of the National Academy of Sciences
印刷版ISSN：0027-8424
电子版ISSN：1091-6490
出版年度：2021
卷号：118
期号：43
DOI：10.1073/pnas.2113715118
语种：English
出版社：The National Academy of Sciences of the United States of America
摘要：Significance
Most shape-morphing materials rely on nonrenewable fossil resources or finely extracted biomaterials, which need strict reaction control, elaborate processing equipment, or prefabricated templates to achieve controllable transformation. To circumvent these challenges, we developed an eco-friendly and scalable strategy for programmable shape evolution that integrates easy-to-process pollen biomass with cost-effective digital printing. Using this approach, specific geometrical features and architectures were customized to build complex materials with user-defined, shape-morphing abilities. These fabrication efforts were complemented by computational simulations to build quantitative and mechanistic insights into the biomaterial’s characteristics for creating complex shapes with methods that are suitable for scalable manufacturing.
We demonstrate how programmable shape evolution and deformation can be induced in plant-based natural materials through standard digital printing technologies. With nonallergenic pollen paper as the substrate material, we show how specific geometrical features and architectures can be custom designed through digital printing of patterns to modulate hygrophobicity, geometry, and complex shapes. These autonomously hygromorphing configurations can be “frozen” by postprocessing coatings to meet the needs of a wide spectrum of uses and applications. Through computational simulations involving the finite element method and accompanying experiments, we develop quantitative insights and a general framework for creating complex shapes in eco-friendly natural materials with potential sustainable applications for scalable manufacturing.
关键词：natural materials; pollen; digital printing; hygromorphing; sustainability
