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  • 标题:Fast synthesis of high surface area bio-based porous carbons for organic pollutant removal
  • 本地全文:下载
  • 作者:Yichen Wu ; Nan Zhang ; Charles-François de Lannoy
  • 期刊名称:MethodsX
  • 印刷版ISSN:2215-0161
  • 电子版ISSN:2215-0161
  • 出版年度:2021
  • 卷号:8
  • 页码:1-8
  • DOI:10.1016/j.mex.2021.101464
  • 语种:English
  • 出版社:Elsevier
  • 摘要:AbstractA fast, facile and one-pot chemical activation method was used to develop porous carbons with high surface area and excellent phenolic micropollutant adsorption performance from renewable precursors. This method was applied to three precursors: naturally abundant, but often underestimated wildfire-damaged boreal peats, corn starch, and cellulose. Porous carbon formation was accomplished through precursor impregnation with ZnCl2powder and their simultaneous pyrolysis under inert N2flow at 400 or 600 °C for 1 h. The maximum adsorption capacities of these bio-sorbents towards a model contaminant,p-nitrophenol, in simulated wastewater were equal to or superior than using a commercial activated carbon (CAC), Norit GSX (> 530 mg/g) over wide initial concentration ranges (20–2000 mg/L).p-nitrophenol adsorption best fitted Freundlich and Redlich-Peterson isotherms, suggesting multilayer chemisorption. Low concentrationp-nitrophenol (20 mg/L) adsorption into the bio-sorbents was rapid in the first 4 h, and could reach high removals (> 98%). The method presented here yielded bio-sorbents with similarly high adsorption performance regardless of the precursor type, while avoiding energy-intensive processing steps during sorbent production. This study gives a useful alternative for manufacturing new sorbents from other upcycled carbonaceous and/or bio-based materials to remove micropollutants and heavy metals.•Fast, single-step chemical activation for manufacturing bio-based porous carbons.•Efficient adsorption towards aqueous phenolic micropollutant from batch studies.•A competitive substitute of charcoal activated carbons for water purification.Graphical AbstractDisplay Omitted
  • 关键词:Boreal peats;Zinc chloride;Chemical activation;Pyrolysis;Isotherm;Kinetics
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