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  • 标题:ADSORPTIONISOTHERM MODELS KINETICS STUDY AND THERMODYNAMIC PARAMETERS OF Hg (II) ADSORPTION BYBIOCHAR PREPARED AT DIFFERENT PYROLYSIS TEMPERATURES
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  • 作者:Guangjie Che ; Shaojing Li
  • 期刊名称:Fresenius Environmental Bulletin
  • 印刷版ISSN:1018-4619
  • 出版年度:2021
  • 卷号:30
  • 期号:12
  • 页码:13020-13026
  • 语种:English
  • 出版社:PSP Publishing
  • 摘要:Biochars were prepared at three different pyrol-ysis temperatures 300 (BC300), 500(BC500),and 650℃C(BC650)using tortoiseshells as raw materials, respectively, and the properties of biochar adsorption of heavy metal Hg2+ were studied. The effects of isothermal adsorption, adsorption kinetics, solution pH and biochar addition dosage on adsorption char-acteristics were analyzed. The results showed that the isothermal adsorption process could be well fit-ted with the Freundich and Langmuir models, and the adsorption kinetics process can be well fitted by the secondary kinetic equation.The best dosage bio-char addition were 2g/L,0.8 g/L,1.2 g/L,and the bestsolution pH was5,6,6 forBC300.BC500.and BC650, respectively.Biochar with high pyrolysis temperature has better adsorption effect than biochar with low pyrolysis temperature, and the adsorption properties of Hg2+ in the solution were obviously different with the preparation temperature.
  • 关键词:Biochar;Pyrolysis temperature;Adsorption Isotherm Models Kinetics;Thermodynamic Parameters
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