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  • 标题:Oxone-Mediated Preparation of Ester Derivatives Using Indium(III) Triflate and Various Alcohols
  • 本地全文:下载
  • 作者:Tomoko Mineno ; Daiki Takano ; Saika Komiya
  • 期刊名称:Green and Sustainable Chemistry
  • 印刷版ISSN:2160-6951
  • 电子版ISSN:2160-696X
  • 出版年度:2022
  • 卷号:12
  • 期号:1
  • 页码:1-8
  • DOI:10.4236/gsc.2022.121001
  • 语种:English
  • 出版社:Scientific Research Publishing
  • 摘要:Esters are known as one of the most fundamental chemical moieties and also essentially useful components, especially for medicinal agents. Herein, using benzaldehyde and its derivatives as starting materials, Oxone-mediated preparation of ester derivatives in the presence of a catalytic amount of indium(III) triflate is described. Alcohols with various chain lengths, which functioned as solvents and substrates, were examined. Overall, the oxidative esterification starting with benzaldehyde derivatives possessing electron withdrawing groups proceeded smoothly and gave sufficient yields, in comparison to the reactions with the derivatives having electron donating groups.
  • 关键词:OxoneOxidative EsterificationBenzaldehyde DerivativesEster DerivativesIndium(III) TriflateAlcohols
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