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  • 标题:Non‐destructive platinum catalyst‐replenishment method for deteriorated polymer electrolyte membrane fuel cells
  • 本地全文:下载
  • 作者:Jaeyeon Kim ; Hongnyung Yoo ; Hyeok Kim
  • 期刊名称:Energy Science & Engineering
  • 电子版ISSN:2050-0505
  • 出版年度:2022
  • 卷号:10
  • 期号:2
  • 页码:414-422
  • DOI:10.1002/ese3.1029
  • 语种:English
  • 出版社:John Wiley & Sons, Ltd.
  • 摘要:Abstract A novel method for replenishing platinum catalysts on an electrolyte membrane of polymer electrolyte membrane fuel cell (PEMFC) is studied. The method injects electrocatalyst‐supplementing ink into a pre‐assembled fuel cell in a simple and non‐destructive manner. For replenishing, straightforward catalyst‐replenishment equipment and corresponding protocol are proposed. The protocol consists of injection, penetration, and purge processes. As a feasibility study, the method is performed on fuel cells with pristine membranes. Target fuel cells for this study include a membrane‐assembled cell without catalyst layers (CLs) (Cell 1) and a cell assembled with a membrane‐coated cathodic CL (Cell 2). An open‐circuit voltage of 0.804 V in Cell 1 and a current of 77 mA in Cell 2 are measured, as supported through electrochemical impedance spectroscopy. Results of energy‐dispersive X‐ray spectroscopy and X‐ray photoelectron spectroscopy also support the presence of platinum catalysts.
  • 关键词:catalyst layer deterioration;catalyst replenishment;electrochemical impedance spectroscopy, fuel cell cleaning;polymer electrolyte membrane fuel cell
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