期刊名称：Journal of Pure and Applied Science and Technology
印刷版ISSN：2231-4202
电子版ISSN：2249-9970
出版年度：2018
卷号：2018
页码：66-73
语种：English
出版社：Natthan Lal Sevarth Samiti
摘要：Kinetic study of the hydrolysis of 3,4-dichloro aniline phosphate triester have been investigated in 30% aqueous dioxan medium by performing kinetic runs in buffer solution from pH 1.24 to 7.46 at (97±0.5)°C temperature. Neutral species of the triester have been found to be reactive in this region. Effect of temperature on the rate of hydrolysis of the triester have been studied to know the molecularity of the reaction. Comparative kinetic rate data and isokinetic relationship plot of some other phosphate triesters of known mechanism were considered to decide whether the hydrolysis of the present triester proceed with P-N or C-N bond fission.
