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  • 标题:Methyl Migrated Cassane-Type Furanoditerpenes of Caesalpinia crista from Myanmar
  • 本地全文:下载
  • 作者:Surya Kant Kalauni ; Suresh Awale ; Yasuhiro Tezuka
  • 期刊名称:Chemical and Pharmaceutical Bulletin
  • 印刷版ISSN:0009-2363
  • 电子版ISSN:1347-5223
  • 出版年度:2005
  • 卷号:53
  • 期号:10
  • 页码:1300-1304
  • DOI:10.1248/cpb.53.1300
  • 出版社:The Pharmaceutical Society of Japan
  • 摘要:

    From the CH2Cl2 extract of seed kernels of Caesalpinia crista from Myanmar, two rare and biogenetically interesting methyl migrated cassane-type furanoditerpenes [caesalpinins MM (1) and MN (2)] and two normal cassane-type furanoditerpenes [caesalpinins MO (3) and MP (4)] have been isolated, together with eight known cassane-type diterpenes, 1-deacetoxy-1-oxocaesalmin C (5), 1-deacetylcaesalmin C (6), caesalmin C (7), bonducellpin C (8), caesaldekarin e (9), 2-acetoxycaesaldekarin e (10), 2-acetoxy-3-deacetoxycaesaldekarin e (11), and norcaesalpinin E (12). Among the known compounds, compounds 5 and 6 were for the first time isolated from a natural source. The structures of these compounds were elucidated by the use of spectroscopic techniques.

  • 关键词:cassane-type furanoditerpene; caesalpinin; Caesalpinia crista ; Myanmar
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