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  • 标题:Neuritogenic Activities of 1-Alkyloxygenipins
  • 本地全文:下载
  • 作者:Hirokazu Suzuki ; Matsumi Yamazaki ; Kenzo Chiba
  • 期刊名称:Chemical and Pharmaceutical Bulletin
  • 印刷版ISSN:0009-2363
  • 电子版ISSN:1347-5223
  • 出版年度:2010
  • 卷号:58
  • 期号:2
  • 页码:168-171
  • DOI:10.1248/cpb.58.168
  • 出版社:The Pharmaceutical Society of Japan
  • 摘要:

    We designed 1-alkyloxygenipins with the aim of improving the stability of genipins based on the structural and electronic properties of genipins, and prepared 1-alkyloxygenipins and examined their neuritogenic activities in PC12h cells. All genipin-derivatives exhibited electronic properties similar to those of genipin and induced significant neurite outgrowth. These compounds will be classified as nitric oxide synthase (NOS) activators (neuritogenic active compounds) since their lowest unoccupied molecular orbital (LUMO)-energies are similar to that of tetrahydrobiopterin (H4B). (1 R )- iso Propyloxygenipin showed activity comparable to that of genipin, and unlike the parent compound genipin, it was found to be physiologically stable in rat liver homogenate.

  • 关键词:genipin; 1- iso propyloxygenipin; neuritogenic activity; neuronal nitric oxide synthase; tetrahydrobiopterin
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