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  • 标题:Synthesis of Cardanol Sulfonate Gemini Surfactant and Enthalpy-Entropy Compensation of Micellization in Aqueous Solutions
  • 本地全文:下载
  • 作者:Weiguang Shi ; Pengxiang Wang ; Cuiqin Li
  • 期刊名称:Open Journal of Applied Sciences
  • 印刷版ISSN:2165-3917
  • 电子版ISSN:2165-3925
  • 出版年度:2014
  • 卷号:04
  • 期号:06
  • 页码:360-365
  • DOI:10.4236/ojapps.2014.46033
  • 语种:English
  • 出版社:Scientific Research Publishing
  • 摘要:A novel cardanol sulfonate Gemini surfactant with high surface properties was synthesized by cashew phenol, 1,3-dibromopropane and chlorosulfonic acid through three steps procedure of etherification, sulfonation and neutralization. A surface tension method was employed to investigate the thermo-dynamic properties of micellization in aqueous solution for cardanol sulfonate Gemini surfactant synthesized in laboratory. As a result, the micellization of cardanol sulfonate Gemini surfactant in aqueous solutions is spontaneous and entropy-driven. The micellization process is enthalpy-entropy compensated with the compensation temperature (Tc) of 308 ± 1 K.
  • 关键词:Cardanol; Gemini Surfactant; Micellization; Enthalpy-Entropy Compensation
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