摘要：SummaryThe outer space (3 K) represents an important thermodynamic resource. It has been known for decades that at nighttime, a sky-facing thermal emitter radiating strongly within the atmospheric transparency window (8–13 μm), can reach below the ambient temperature. In recent studies, thermoelectric generators were used to harness this temperature difference between the emitter and ambient to generate electricity. However, the demonstrated power density has been limited by parasitic thermal losses. Here we show that these parasitic losses can be reduced through thermal engineering. We present a simple model showing the optimum power density can be approached by controlling the relation between the emitter area and the thermal resistance of the thermoelectric generator. We show that the stacking of multiple thermoelectric generators is an effective way to approach this optimum. We experimentally demonstrate a generated electric power density >100 mW/m2, representing > 2-fold improvement over the previous results for nighttime radiative cooling.Graphical abstractDisplay OmittedHighlights•We demonstrate >100 mW/m2power generation at nighttime from radiative cooling•This power density is four times over the previous record•Key is to optimize outgoing thermal radiation over parasitic heat transfer channels•Proposed model allows system design with maximal power generation at nighttimeEnergy sustainability; Heat Transfer; Thermal property.
