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  • 标题:Metabolic Products of Fungi. XIII. The Structure of Oxyskyrin.
  • 本地全文:下载
  • 作者:Shoji Shibata ; Michio Takido ; Akihiro Ohta
  • 期刊名称:Chemical and Pharmaceutical Bulletin
  • 印刷版ISSN:0009-2363
  • 电子版ISSN:1347-5223
  • 出版年度:1957
  • 卷号:5
  • 期号:6
  • 页码:573-575
  • DOI:10.1248/cpb1953.5.573
  • 出版社:The Pharmaceutical Society of Japan
  • 摘要:The pigment B, isolated from Penicillium islandicum SOPP, N. R. R. L. 1175, and also found in the mycelium of Endothia parasitica ANDERSON ET ANDERSON, was studied. The pigment B which was named oxyskyrin gave a molecular formula, C30H18O11, and yielded heptaacetate and heptabenzoate. On reductive cleavage with alkaline sodium dithionite, oxyskyrin was decomposed to give emodin and ω-hydroxyemodin. On oxidation with chromium trioxide, oxyskyrin heptaacetate was converted into skyric acid hexaacetate. Consequently, oxyskyrin was formulated as 2, 4, 5, 2', 4', 5'-hexahydroxy-7-methyl-7'-hydroxymethyl-bianthraquinone-(1, 1').
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