The purpose of this study was to examine the relationship between alienation and the value system. Alienation Scale developed by Miyashita and Kobayashi, and twenty-six items measuring the value system were administered to 258 university students. The main findings were as follows: (1) The items measuring the value system were analyzed and extracted three factors, that is, the intention for human environment, for matter and machine, and for interpersonal relationship; (2) Correlations were performed between alienation and those three factors, and gave the following results: (a) Alienation had a significant positive correlation with the intention for matter and machine, and negative correlations with the intention for human environment and for interpersonal relationship; (b) Alienation had a significant negative correlation with Ss' cognition of social system's accounting for much of the intention for interpersonal relationship; and (c) Alienation had a significant positive correlation with self-social cognition discrepancy of the intention for interpersonal relationship. These results almost supported the hypotheses.