The accurate information on vegetation-covered area as a pervious surface is necessary to improve the accuracy of runoff analysis for non-point pollutant loading and groundwater recharge in urban region. In this study, practical bisection method for distinguishing vegetation from non-vegetation in urban regions was proposed. The Green Bias Index (GBI) which is derived from the strong relationship between the red edge and green edge in high resolution satellite image stands for the pigment property of vegetation as the bias terms of the green reflectance between near-infrared and red reflectance. Through the application of the GBI in study area, the vegetation higher than 99.7% to ground truth data could be identified, while the misidentification rate from non-vegetation is lower than 0.2% and 0.1% in roof and road, respectively. The width error between identified and measured vegetations was zero to one pixel for eleven sites selected in the study area. Finally, the spatial and temporal variance of GBI was investigated with five satellite images obtained on different date and location.