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  • 标题:カラー写真像を形成しているアゾメチン型色素溶液の光変退色; モデルマゼンタ色素-カルボニル化合物-アルコールの脱気溶液の光退色生成物の同定
  • 本地全文:下载
  • 作者:三輪 卓司 ; 押見 隆則 ; 旭 洋一
  • 期刊名称:日本写真学会誌
  • 印刷版ISSN:0369-5662
  • 电子版ISSN:1884-5932
  • 出版年度:1989
  • 卷号:52
  • 期号:6
  • 页码:532-539
  • DOI:10.11454/photogrst1964.52.532
  • 出版社:The Society of Photographic Science and Technolgy of Japan
  • 摘要:

    In order to elucidate photo-fading mechanisms of azomethine dyes forming color photographic images, identification of products in degassed solutions of model magenta dyes-carbonyl compounds (CCPD)-alcohols by photo-excitation of CCPD with near ultraviolet rays was made. The used dyes were 3-methyl-1-phenyl-4-(p-diethylamino-phenyl)-imino-2-pyrazoline-5-one (Magenta Dye 1) and 1, 3-diphenyl-4-(p-diethylamino-phenyl)-imino-2-pyrazoline-5-one (Magneta Dye 2). The products were separated throughout in a vacuum system, and NMR and mass spectra were measured. The products were identified as leuco forms of the dyes. Moreover it was confirmed that the leuco form of Magenta Dye 1 was 3-methyl-1-phenyl-4-(p-diethylamino-phenyl)-amino-3-pyrazoline-5-one and the leuco form of Magneta Dye 2 was 1, 3-diphenyl-4-(p-diethylamino-phenyl)-amino-3-pyrazoline-5-one. These results are consistent with and support strongly the previously published mechanisms in which ketyl radicals of CCPD initiate reduction of the dyes.

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