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  • 标题:カラー写真像を形成しているインドアニリン型色素溶液の光変退色; モデルシアン色素-カルボニル化合物-アルコールの脱気溶液の光退色生成物の同定と脱クロル反応の機構
  • 本地全文:下载
  • 作者:三輪 卓司 ; 押見 隆則 ; 旭 洋一
  • 期刊名称:日本写真学会誌
  • 印刷版ISSN:0369-5662
  • 电子版ISSN:1884-5932
  • 出版年度:1989
  • 卷号:52
  • 期号:6
  • 页码:540-549
  • DOI:10.11454/photogrst1964.52.540
  • 出版社:The Society of Photographic Science and Technolgy of Japan
  • 摘要:

    In order to elucidate photo-fading mechanism of indoaniline type dye forming color photographic image, photo-fading products in degassed ethanol solutions of model cyan dye with carbonyl compounds were identified. The used model cyan dyes were 2-chloro-N-(4-diethylamino-phenyl)-pnaphthoquinone monoimine (Cyan Dye 1) and N-(4-diethylamino-phenyl)-p-naphthoquinone monoimine (Cyan Dye 2). Separation of products and preparation of samples for NMR and mass measurements were carried out in an all degassed system. The product in Cyan Dye 2 solutions was identified as leuco form by addition of two hydrogen atoms to Cyan Dye 2 and 4-(4-diethylamino-phenyl)-amino-1-naphthol. The product in Cyan Dye 1 solutions was a salt of the same compound as the one in Cyan Dye 2 solutions with hydrochloric acid. During photo-fading of Cyan Dye 1 solutions, absorption spectra shifted to short wave-length gradually and it was confirmed that the blue shift resulted from dechlorination. Reaction mechanism was also examined and it was estimated that reactive species for dechlorination was a radical intermediate which was produced by addition of one hydrogen atom to azomethine group of Cyan Dye 1 by ketyl radical of carbonyl compound.

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