摘要：Although faster transport velocities of colloid-associated actinides, bacteria, and virus than nonreactive solutes have been observed in laboratory and field experiments, some questions still need to be answered. To accurately determine the relative velocity ( U Pu/ U T) of 239Pu and tritium representative of the bulk water, a conceptual model of electrostatic interactions coupled with the parabolic water velocity profile in pore channels is developed. Based on the expression for U Pu/ U T derived from this model, we study the effects of water flow rates and ionic strengths on the U Pu/ U T. Also, the velocity relationship between Pu, tritium and Sr2+ is explored. The results show that U Pu/ U T increased fairly linearly with decreasing water flow rates; U Pu/ U T declined approximately exponentially with increasing Na+ concentrations; the charge properties of colloid-associated Pu (negative), tritium (neutral) and Sr2+ (positive) had a close association with their transport velocities as U Pu : U T : U Sr2+ = 1.41 : 1 : 0.579.
