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  • 标题:Scalable Synthesis of Nano-Silicon from Beach Sand for Long Cycle Life Li-ion Batteries
  • 本地全文:下载
  • 作者:Zachary Favors ; Wei Wang ; Hamed Hosseini Bay
  • 期刊名称:Scientific Reports
  • 电子版ISSN:2045-2322
  • 出版年度:2014
  • 卷号:4
  • DOI:10.1038/srep05623
  • 出版社:Springer Nature
  • 摘要:Herein, porous nano-silicon has been synthesized via a highly scalable heat scavenger-assisted magnesiothermic reduction of beach sand. This environmentally benign, highly abundant, and low cost SiO2 source allows for production of nano-silicon at the industry level with excellent electrochemical performance as an anode material for Li-ion batteries. The addition of NaCl, as an effective heat scavenger for the highly exothermic magnesium reduction process, promotes the formation of an interconnected 3D network of nano-silicon with a thickness of 8-10 nm. Carbon coated nano-silicon electrodes achieve remarkable electrochemical performance with a capacity of 1024 mAhg−1 at 2 Ag−1 after 1000 cycles.
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