标题：ZnO Nanocomposites Modified by Hydrophobic and Hydrophilic Silanes with Dramatically Enhanced Tunable Fluorescence and Aqueous Ultrastability toward Biological Imaging Applications
摘要：Multicolor ZnO quantum dots (QDs) were synthesized and further modified with hydrophobic hexadecyltrimethoxysilane (HDS) and then hydrophilic aminopropyltriethoxysilane (APS) bilayers, resulting in amine-functionalized ZnO@HDS@APS nanocomposites with tunable fluorescence from blue to green yellow. Systematic investigations verify that the resulting ZnO@HDS@APS could display extremely high stability in aqueous media and unexpectedly, dramatically-enhanced fluorescence intensities, which are about 10-fold higher than those of bare ZnO QDs. The feasibility of the as-prepared ZnO nanocomposites for blood, cell, and tissue imaging was preliminarily demonstrated, promising the wide bio-applications for cell or tissue imaging, proteome analysis, drug delivery, and molecular labeling.
