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  • 标题:Molecular Design of Near-IR Dyes with Different Surface Energy for Selective Loading to the Heterojunction in Blend Films
  • 本地全文:下载
  • 作者:Huajun Xu ; Takaaki Wada ; Hideo Ohkita
  • 期刊名称:Scientific Reports
  • 电子版ISSN:2045-2322
  • 出版年度:2015
  • 卷号:5
  • DOI:10.1038/srep09321
  • 出版社:Springer Nature
  • 摘要:We have synthesized three silicon phthalocyanine dyes with different hydrophobic substituents in order to control surface energy in the solid state, aiming at selective loading of the dyes into blend films of poly(3-hexylthiophene) (P3HT) and polystyrene (PS). These three dyes are differently located at P3HT domains, at P3HT/PS interface, and at PS domains, respectively, which are fully consistent with the locations predicted by the wetting coefficient derived from the surface energy of each material.
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